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Worldwide Refinery Processing Review (Individual Technology)

CRUDE TREATING AND DESALTING
Publication date:1Q 2015
Item#: B1006

Crude Blending, Treating, and Desalting

With the consistent changes to the crude supply being processed across the globe, refiners are facing new challenges to ensure the safe and reliable operation of their entire facility. Crudes that are considered opportunistic due to their low cost are highly desired for refiners, but without proper treatment these crudes can severely damage downstream units and equipment. Furthermore, with the large variety of crude available, refiners are seeking the ideal blends of various crudes to economically optimize their refineries while resisting solid and salt accumulation, corrosion and fouling to essential equipment (due mainly to acidic compounds and asphaltene deposition). Whether it is heavy, high TAN crudes or blends of various crude sources, these feedstocks require treatment prior to reaching the CDU to keep operations smooth throughout processing. This is where pretreatment methods such as desalting and the use of chemical additives play a major role.

Preparing crude for the CDU mainly involves electrostatic desalting, which removes water and water-soluble salts. This process is also supported by additional techniques including the upstream removal of hydrogen sulfide by the addition of so-called "H2S scavengers," metal-removal additives, asphaltene dispersants, base addition to reduce naphthenic acid content of high-acid crudes (HACs), solids filtration, and chemical demulsifiers. Improved crude blending operations upstream of the desalter may help alleviate some of the difficulties associated with these preparation steps, and at the very least, a more thorough understanding of the crude feedstock slate will be beneficial for optimizing crude treating and desalting activities.

The ability to predict crude blend properties has proven to be the most efficient means of preventing damage to refining equipment, as refiners can determine which ratios offer the ideal properties for their refinery, or they can optimize the crude pretreatment process to combat the expected issues. This involves the use of both software-related solutions and testing/analysis of crude samples. Both approaches have seen new developments in recent years, and can be used together to optimize a blend for a particular refinery. There are a growing number of chemical products available to assist refiners with overcoming desalting problems. Chemical companies market a range of emulsion breakers tailored for desalter operations as well as extensive chemical treatment packages to aid in metals removal; inhibit corrosion, fouling, and scaling; prevent foaming; and remove sulfur. A number of chemical companies also provide reverse emulsion breakers to treat oily brine effluent upstream of the wastewater treatment plant. Corrosion control technologies that include monitoring and predictive technique are also available to be used when processing high-acid crudes. The crude blending, treating, and desalting also features the latest trends and technology offerings, including:

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The Review is sold for the exclusive use of the subscriber. No other use, duplication, or publication of the Review or any part contained therein is permitted without written consent from Hydrocarbon Publishing Company, P.O. Box 661, Southeastern PA 19399 (USA).

crude, crude distillation, opportunity crudes, tight oil, oilsands, dumbbell crudes, heavy crude, extra-heavy crude, high-acid crude, crude blending, crude treating, desalter, desalting, electrostatic desalting, incompatibility, TAN, API gravity, asphaltenes, asphaltenes precipitation, CDU, ADU, H2S scavengers, static mixers, sonic energy, additives, mercaptans, naphthenic acid, wastewater, emulsion breakers, demulsifier, stability, brine effluent treating, corrosion, water wash, metals removal, neutralizer, viscosity